Intramolecular C-H activation in alkaline-earth metal complexes

被引：79

作者：

Harder, S ^{[1
]}

机构：

[1] Univ Konstanz, Fachbereich Chem, D-78457 Constance, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 29期

关键词：

alkaline-earth metals; calcium; carbanions; C-H activation; cyclometalation;

D O I：

10.1002/anie.200351055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A heteroleptic benzylcalcium complex decomposes by means of C-H activation (see picture), a reaction typical for d0-metal complexes. This finding closes the gap between the chemistry of the heavier alkaline-earth and the early d- and f-block metals. The product, a dimeric calcium complex, was characterized by X-ray crystallography.

引用

页码：3430 / 3434

页数：5

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