Pd nanoparticles in silica hollow spheres with mesoporous walls: a nanoreactor with extremely high activity

被引:270
作者
Chen, Zhe [1 ]
Cui, Zhi-Min [2 ]
Niu, Fang [1 ]
Jiang, Lei [2 ]
Song, Wei-Guo [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China
[2] Beihang Univ, Sch Chem & Environm, Beijing 100191, Peoples R China
基金
中国国家自然科学基金;
关键词
NOBLE-METAL NANOPARTICLES; CROSS-COUPLING REACTIONS; PALLADIUM NANOPARTICLES; STABILITY; CATALYSIS; SHELL; NANOCRYSTALS; FABRICATION; COMPLEXES;
D O I
10.1039/c0cc01786h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A true nanoreactor composed of mesoporous silica hollow spheres and Pd nanoparticles residing inside the spheres shows superior activity in Suzuki coupling reactions with 99.5% yield in 3 min.
引用
收藏
页码:6524 / 6526
页数:3
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