Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure?

被引：128

作者：

Wang, YT

Tong, ML

Fan, HH

Wang, HZ

Chen, XM ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China

来源：

DALTON TRANSACTIONS | 2005年 / 03期

关键词：

D O I：

10.1039/b416412a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homochiral/heterochiral crystallizations of helical chiral polymer chains bridged by achiral poly-pyridyl ligands dependent on the structures of the bridging ligands and independent on the solvent are described, implying a possible strategy to design achiral crystals of helical chains using chiral bridging ligands.

引用

页码：424 / 426

页数：3

共 37 条

[1] Let's twist again - Double-stranded, triple-stranded, and circular helicates [J].

Albrecht, M .

CHEMICAL REVIEWS, 2001, 101 (11) :3457-3497

[2] [Ni2O(L-Asp)(H2O)2]•4H2O:: A homochiral 1D helical chain hybrid compound with extended Ni-O-Ni bonding [J].

Anokhina, EV ;

Jacobson, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) :3044-3045

[3]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[4]

2-Z

[5] Molecular squares, rectangles and infinite helical chains utilising the simple 'corner' ligand 4-(2-pyridyl)-pyrimidine [J].

Beauchamp, DA ;

Loeb, SJ .

CHEMICAL COMMUNICATIONS, 2002, (21) :2484-2485

[6]

Chen XM, 2002, CHEM-EUR J, V8, P4811, DOI 10.1002/1521-3765(20021018)8:20<4811::AID-CHEM4811>3.0.CO

[7]

2-R

[8] A homochiral triple helix constructed from an axially chiral bipyridine [J].

Cui, Y ;

Ngo, HL ;

Lin, WB .

CHEMICAL COMMUNICATIONS, 2003, (12) :1388-1389

[9] Preparation of resolved fourfold symmetric amphiphilic helices using chiral metallacrown building blocks [J].

Cutland-Van Noord, AD ;

Kampf, JW ;

Pecoraro, VL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (24) :4667-4670

[10] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

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