Iron-catalyzed cross-coupling of alkyl halides with alkenyl grignard reagents

被引：185

作者：

Guerinot, Amandine ^{[1
]}

Reymond, Sebastien ^{[1
]}

Cossy, Janine ^{[1
]}

机构：

[1] CNRS, Chim Organ Lab, ESPCI, F-75231 Paris 05, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 34期

关键词：

alkyl halides; Grignard reagents; homogeneous catalysis; iron; sustainable chemistry;

D O I：

10.1002/anie.200702206

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Cheap and safe: An iron-catalyzed cross-coupling reaction between alkyl halides and alkenyl Grignard reagents is described. This C-C bond coupling reaction is promoted by the cheap and nontoxic FeCl3 and displays good tolerance against various functional groups. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6521 / 6524

页数：4

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