Aminocarbene complexes derived from nucleophilic addition to isocyanide ligands

被引：218

作者：

Michelin, RA

Pombeiro, AJL

Fátima, M

da Silva, CG

机构：

[1] Univ Padua, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy

[2] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 218卷

关键词：

aminocarbene complexes; heterocyclic aminocarbene complexes; isocyanide complexes; nucleophilic addition reactions; cycloaddition reactions;

D O I：

10.1016/S0010-8545(01)80004-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Isocyanides ligating medium to high-valent electron-poor metal centers can undergo activation toward alpha -nucleophilic addition to afford a variety of aminocarbene complexes with either heterocyclic or acyclic aminocarbene ligands. These reactions as well as the structural and electronic properties of such products are reviewed. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：75 / 112

页数：38

相关论文

共 154 条

[1] SYNTHESES AND REACTIONS OF ACYCLIC AND CYCLIC CARBENE COMPLEXES CIS-[MI(=CMENHME)(CO)2(ETA-C5H5)](M=MO OR W) AND CIS-[MI(=C(CH2)NNME)(CO)2(ETA-C5H5)](M=MO,N=3 OR 4-M=W,N=3) OBTAINED THROUGH ALKYL MIGRATION TO METHYL ISOCYANIDE COORDINATED TO MOLYBDENUM OR TUNGSTEN - X-RAY STRUCTURE OF CIS-[MOI(=C(CH2)3NME)-(CO)2(ETA-C5H5)]O [J].

ADAMS, H ;

BAILEY, NA ;

OSBORN, VA ;

WINTER, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10) :2127-2135

[2] SYNTHESIS AND PHASE-BEHAVIOR OF MESOMORPHIC TRANSITION-METAL COMPLEXES OF ALKOXYDITHIOBENZOATES - CRYSTAL AND MOLECULAR-STRUCTURE OF 3 METAL ALKOXYDITHIOBENZOATES [J].

ADAMS, H ;

ALBENIZ, AC ;

BAILEY, NA ;

BRUCE, DW ;

CHERODIAN, AS ;

DHILLON, R ;

DUNMUR, DA ;

ESPINET, P ;

FEIJOO, JL ;

LALINDE, E ;

MAITLIS, PM ;

RICHARDSON, RM ;

UNGAR, G .

JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (05) :843-855

[3]

AHN SY, 1991, J ORGANOMET CHEM, V418, P365, DOI 10.1016/0022-328X(91)80222-6

[4]

[Anonymous], 1982, REACTION COORDINATED

[5] A STABLE CRYSTALLINE CARBENE [J].

ARDUENGO, AJ ;

HARLOW, RL ;

KLINE, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) :361-363

[6] Looking for stable carbenes: The difficulty in starting anew [J].

Arduengo, AJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) :913-921

[7] Organic syntheses via transition metal complexes .84. Stereoselective route to (aminoalkynylcarbene)chromium complexes via addition of (1-alkynyl)lithium compounds to isocyanide ligands [J].

Aumann, R ;

Jasper, B ;

Frahlich, R .

ORGANOMETALLICS, 1996, 15 (07) :1942-1950

[8]

BADDLEY W, 1951, J CHEM SOC, P1589

[9] A AU-197 MOSSBAUER STUDY OF A SERIES OF ISOCYANIDE, CARBENE, OR METHANIDE DERIVATIVES OF GOLD - THE CRYSTAL-STRUCTURE OF TRANS, TRANS-[(PARA-MEC6H4NHCOET)2AU]CIO4 AND CIS, CIS-[(PARA-MEC6H4NHCOET)2AU]CIO4 AND OF CIS, TRANS-(PARA-MEC6H4NHCOET)AUCL [J].

BANDITELLI, G ;

BONATI, F ;

CALOGERO, S ;

VALLE, G ;

WAGNER, FE ;

WORDEL, R .

ORGANOMETALLICS, 1986, 5 (07) :1346-1352

[10] CHEMISTRY OF HYDROGEN ISOCYANIDE .1. REACTIONS OF [CR(CO)5(CNH)], [W(CO)5(CNH)] WITH EPOXIDES [J].

BAR, E ;

VOLKL, A ;

BECK, F ;

FEHLHAMMER, WP ;

ROBERT, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (04) :863-868

← 1 2 3 4 5 6 7 8 9 10 →