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Aminocarbene complexes derived from nucleophilic addition to isocyanide ligands

被引：218
作者：
Michelin, RA
Pombeiro, AJL
Fátima, M
da Silva, CG
机构：
[1] Univ Padua, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy
[2] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal
来源：
COORDINATION CHEMISTRY REVIEWS | 2001年 / 218卷
关键词：
aminocarbene complexes; heterocyclic aminocarbene complexes; isocyanide complexes; nucleophilic addition reactions; cycloaddition reactions;
D O I：
10.1016/S0010-8545(01)80004-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Isocyanides ligating medium to high-valent electron-poor metal centers can undergo activation toward alpha -nucleophilic addition to afford a variety of aminocarbene complexes with either heterocyclic or acyclic aminocarbene ligands. These reactions as well as the structural and electronic properties of such products are reviewed. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：75 / 112
页数：38
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