Click Syntheses of 1,2,3-Triazolylbiferrocenyl Dendrimers and the Selective Roles of the Inner and Outer Ferrocenyl Groups in the Redox Recognition of ATP2- and Pd2+

被引：88

作者：

Djeda, Rodrigue ^{[1
]}

Rapakousiou, Amalia ^{[1
]}

Liang, Liyuan ^{[1
]}

Guidolin, Nicola ^{[2
]}

Ruiz, Jaime ^{[1
]}

Astruc, Didier ^{[1
]}

机构：

[1] Univ Bordeaux 1, Inst Mol Sci, CNRS, UMR 5255, F-33405 Talence, France

[2] Univ Bordeaux 1, Lab Chim Polymeres Organ, CNRS, UMR 5629, F-33607 Pessac, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 44期

关键词：

dendrimers; metallocenes; mixed-valent compounds; nanoparticles; redox chemistry; ATTACHED GOLD NANOPARTICLES; ORGANIC-SOLID STATE; MOLECULAR ELECTRONICS; INTERVALENCE TRANSFER; DELTA-E-1/2; VALUES; AMBIENT CONDITIONS; BIFERROCENE; TRANSITION; ELECTRODEPOSITION; PALLADIUM;

D O I：

10.1002/anie.201004756

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This way and that: Triazolylbiferrocenyl dendrimers can be synthesized with up to 729 termini. Oxidation results in isolable mixed-valence dendrimers (see picture). In electrochemical studies, these species can recognize ATP 2- and PdII, and they can be used to stabilize Pd nanoparticle catalysts. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8152 / 8156

页数：5

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