Microporous Metal-Organic Framework Based on Supermolecular Building Blocks (SBBs): Structure Analysis and Selective Gas Adsorption Properties

被引：67

作者：

Chang, Ze ^{[1
]}

Zhang, Da-Shuai ^{[1
]}

Hu, Tong-Liang ^{[1
]}

Bu, Xian-He ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin Key Lab Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 06期

关键词：

HYDROGEN STORAGE; COORDINATION POLYMER; SORPTION PROPERTIES; NETWORK; DESIGN; NET; TOPOLOGY; CHANNELS; SOLIDS; LIGAND;

D O I：

10.1021/cg200043a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new supermolecular building blocks (SBBs) based microporous metal-organic framework (MOP) was prepared with both 1,3,5-benzenetricarboxylic acid (H(3)btc) and 2,4,6-tris(4-pyridyl)-1,3,5-triazine (tpt) as ligands. The obtained Co-II MOF reveals an uncommon ftw-a-like structure from the assembly of cubohemioctahedra SBBs under the direction of tpt and exhibits selective gas adsorption properties depending on gas molecule diameter and temperature which might have application in gas separation purposes.

引用

页码：2050 / 2053

页数：4

共 42 条

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