Structure and Charge Control in Metal-Organic Frameworks Based on the Tetrahedral Ligand Tetrakis(4-tetrazolylphenyl)methane

被引：99

作者：

Dinca, Mircea ^{[1
]}

Dailly, Anne ^{[2
]}

Long, Jeffrey R. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] GM Corp, Chem & Environm Sci Lab, Warren, MI 48090 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2008年 / 14卷 / 33期

关键词：

copper; manganese; metal-organic frameworks; microporous materials; tetrazoles;

D O I：

10.1002/chem.200801336

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Use of the tetrahedral ligand tetra kis(4-tetrazolylphenyl)methane enabled isolation of two three-dimensional metal-organic frameworks featuring 4,6- and 4,8-connected nets related to the structures of garnet and fluorite with the formulae Mn-6-(ttpm)(3)center dot 5DMF center dot 3H(2)O (1) and Cu-[(CU4Cl)(ttpm)(2)](2)center dot CuCl2 center dot 5DMF center dot 11H(2)O (2) (H(4)ttpm=tetrakis(4-tetrazolylphenyl)methane). The fluorite-type solid 2 displays an unprecedented post-synthetic transformation in which the negative charge of the framework is reduced by extraction of copper(II) chloride. Desolvation of this compound generates Cu-4(ttpm)(2)center dot 0.7CuCl(2) (2d), a microporous material exhibiting a high surface area and significant hydrogen uptake.

引用

页码：10280 / 10285

页数：6

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