Synthesis, characterisation and reaction chemistry of organotin-substituted bis(thiotetrazoles): supramolecular metallotetrazole structures containing hard and soft donors

被引：60

作者：

Bhandari, S ^{[1
]}

Mahon, MF ^{[1
]}

McGinley, JG ^{[1
]}

Molloy, KC ^{[1
]}

Roper, CEE ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 20期

关键词：

D O I：

10.1039/a804928i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four new organotin thiotetrazoles 1,4-(R3SnSCN4)(2)C6H4 (R = Me, Et, Bu or Ph), along with their triphenyllead. diphenylthallium and phenylmercury analogues, have been synthesized. The supramolecular structure of 1,4-(Bu3SnSCN4)(2)C6H4 has been found to consist of a 2-D sheet arrangement containing 32-membered (C4NCSSnN2CSSnN3)(2) rings. In contrast. 1,4-(Me3SnSCN4)(2)C6H4 crystallises as a bis(methanol) solvate in which 14-membered (SnSCN2HO)(2) rings are linked through hydrogen bonds into a 1-D polymer.

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页码：3425 / 3430

页数：6

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