Neutron powder diffraction refinement of ilmenite-type bismuth oxides:: ABiO3 (A = Na, Ag)

被引：75

作者：

Kumada, N

Kinomura, N

Sleight, AW

机构：

[1] Yamaguchi Univ, Fac Engn, Kofu, Yamanashi 4008511, Japan

[2] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA

来源：

MATERIALS RESEARCH BULLETIN | 2000年 / 35卷 / 14-15期

关键词：

oxides; crystal structure;

D O I：

10.1016/S0025-5408(00)00453-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The crystal structures of the ilmenite-type oxides, ABiO(3) (A = Na,Ag) were refined using neutron diffraction data. NaBiO3 was prepared by dehydration of NaBiO3. nH(2)O, and AgBiO3 was prepared by ion exchange of NaBiO3. nH(2)O with Ag+ ions. The hexagonal lattice parameters are a = 5.5672(4) and c = 15.989(1) Angstrom for NaBiO(3)and a = 5.641(1) and c = 16.118(2)Angstrom for AgBiO3. The final R factors were R-WP = 11.6 and G(P) = 9.18% for NaBiO3, and R-WP = 7.96 and R-P = 6.12% for AgBiO3. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2397 / 2402

页数：6

共 22 条

[11] CRYSTAL-STRUCTURE OF BI2O4 WITH BETA-SB2O4-TYPE STRUCTURE [J].