Sulfonyl esters .7. The second and third sequences in the trithioorthoformate reaction

被引：3

作者：

Ginige, KA ^{[1
]}

Goehl, JE ^{[1
]}

Langler, RF ^{[1
]}

机构：

[1] MT ALLISON UNIV,DEPT CHEM,SACKVILLE,NB E0A 3C0,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1996年 / 74卷 / 09期

关键词：

single electron transfer; sulfonate esters; sulfenes;

D O I：

10.1139/v96-181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A previous report has established the intermediacy of a sulfide-sulfonate ester in the one-pot conversion of an aryl mercaptan and a sulfonate ester into the corresponding trithioorthoformate. This report describes evidence for the sequential intermediacy of a bissulfide-sulfonate ester and a dithiosulfene in the conversion of the sulfide-sulfonate ester into the trithioorthoformate. A new sulfonate ester is shown to give the highest yield of trithioorthoformate.

引用

页码：1638 / 1648

页数：11

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