Base-catalysed oxidative [3+2]cycloaddition reaction of [60]fullerene with beta-dicarbonyl compounds

被引：32

作者：

Ohno, M ^{[1
]}

Yashiro, A ^{[1
]}

Eguchi, S ^{[1
]}

机构：

[1] NAGOYA UNIV, FAC ENGN, INST APPL ORGAN CHEM, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 03期

关键词：

D O I：

10.1039/cc9960000291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ambiphilic nature of beta-keto esters and beta-diketones allows cycloaddition to C-60 in the presence of piperidine to give dihydrofuran-fused C-60 derivatives via oxidative cyclization complimentary to the concerted process.

引用

页码：291 / 292

页数：2