The effect of particle size on the discharge performance of a nickel-metal hydride cell

被引:21
作者
Heikonen, JM [1 ]
Ploehn, HJ [1 ]
White, RE [1 ]
机构
[1] Univ S Carolina, Dept Chem Engn, Columbia, SC 29208 USA
关键词
D O I
10.1149/1.1838565
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We investigate the effect of particle size on the discharge performance of a nickel-metal hydride cell with a mathematical model. Electrodes with uniform as well as with nonuniform particle sizes are studied. With uniform particle size, the dependence of the particle-to-particle resistance on the particle size is taken into account. The optimal particle size depends on the discharge rate. Moreover, we show that under certain conditions it is advantageous to use a nonuniform particle size. In general, the higher the discharge current density, the more the particle size affects the electrode performance.
引用
收藏
页码:1840 / 1848
页数:9
相关论文
共 13 条
[11]   A MATHEMATICAL-MODEL FOR METAL HYDRIDE ELECTRODES [J].
VIITANEN, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (04) :936-942
[12]   ELECTROCHEMICAL DETERMINATION OF THE DIFFUSION-COEFFICIENT OF HYDROGEN THROUGH AN LANI4.25AL0.75 ELECTRODE IN ALKALINE AQUEOUS-SOLUTION [J].
ZHENG, G ;
POPOV, BN ;
WHITE, RE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (08) :2695-2698
[13]  
ZHENG G, IN PRESS J APPL ELEC