Rate study of reduction of 2-heptanone with samarium iodide by gas chromatography

被引：13

作者：

Fuh, MRS ^{[1
]}

Lin, TY ^{[1
]}

Chang, SC ^{[1
]}

机构：

[1] Soochow Univ, Dept Chem, Taipei, Taiwan

来源：

TALANTA | 1998年 / 46卷 / 05期

关键词：

2-heptanone; samarium iodide; gas chromatography;

D O I：

10.1016/S0039-9140(97)00328-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This article describes a newly developed method of gas chromatography (GC) for the rate study of the reduction of organic compounds by samarium iodide. Solvent extraction was used to reduce the interference of GC analysis by inorganic species. Adequate recoveries ranged from 88.3 to 94.5% and good linearity ranging from 0.1 to 2.1 mM was determined. An internal standard, decane, was used to enhance the precision of this test. The coefficient variations of intra-day and inter-day ranged from 0.22 to 3.00%. The stability of the reacted sample was also assessed. In addition, the reaction rates of the reduction of 2-heptanone by samarium iodide in the presence of hexamethylphosphoramide were examined. The results presented hererin demonstrate the utility of this method in kinetic studies. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：861 / 866

页数：6

共 12 条

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[2]

CURRAN DP, 1992, SYNLETT, P943

[3] DIVALENT LANTHANIDE DERIVATIVES IN ORGANIC-SYNTHESIS .1. MILD PREPARATION OF SMI2 AND YBI2 AND THEIR USE AS REDUCING OR COUPLING AGENTS [J].