Comparison of exhaust emissions from Swedish environmental classified diesel fuel (MK1) and European Program on Emissions, Fuels and Engine Technologies (EPEFE) reference fuel:: A chemical and biological characterization. with viewpoints on cancer risk

被引:86
作者
Westerholm, R [1 ]
Christensen, A
Törnqvist, M
Ehrenberg, L
Rannug, U
Sjögren, M
Rafter, J
Soontjens, C
Almén, J
Grägg, K
机构
[1] Univ Stockholm, Arrhenius Lab, Dept Analyt Chem, S-10691 Stockholm, Sweden
[2] Univ Stockholm, Wallenberg Lab, Dept Environm Chem, S-10691 Stockholm, Sweden
[3] Univ Stockholm, Wallenberg Lab, Dept Genet & Cellular Toxicol, S-10691 Stockholm, Sweden
[4] Karolinska Inst, Novum, Dept Med Nutr, S-14186 Huddinge, Sweden
[5] MTC AB, S-13623 Haninge, Sweden
关键词
D O I
10.1021/es000113i
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Diesel fuels, classified as environmentally friendly, have been available on the Swedish market sin ce 1991. Th e Swedish diesel fuel classification is based upon the specification of selected fuel composition and physical properties to reduce potential environmental and health effects from direct human exposure to exhaust. The objective of the present investigation was to compare the most stringent, environmentally classified Swedish diesel fuel (MK1) to the reference diesel fuel used in the "European Program on Emissions, Fuels and Engine Technologies" (EPEFE) program. The study compares measurements of regulated emissions, unregulated emissions, and biological tests from a Volvo truck using these fuels. The regulated emissions from these two fuels (MK1 vs EPEFE) were CO (-2.2%), HC (12%), NOx(-11%), and particulates(-11%). The emissions of aldehydes, alkenes, and carbon dioxide were basically equivalent. The emissions of particle-associated polycyclic aromatic hydrocarbons (PAHs) and I-nitropyrene were 88% and 98% lower than those of the EPEFE fuel, respectively. The emissions of semi-volatile PAHs and l-nitropyrene were 77% and 80% lower than those from the EPEFE fuel, respectively. The reduction in mutagenicity of the particle extract Varied from -75 to -90%, depending on the tester strain. The reduction of mutagenicity of the semi-volatile extract varied between -40 and -60%. Furthermore, the dioxin receptor binding activity was a factor of 8 times lower in the particle extracts and a factor of 4 times lower in the semi-volatile extract than that of the EPEFE fuel. In conclusion, the MK1 fuel was found to be more environmentally friendly than the EPEFE fuel.
引用
收藏
页码:1748 / 1754
页数:7
相关论文
共 41 条
[21]  
National Institute of Occupational Health, 1987, 1030 NAT I OCC HLTH, V1030
[22]   Urban air pollution and lung cancer in Stockholm [J].
Nyberg, F ;
Gustavsson, P ;
Järup, L ;
Bellander, T ;
Berglind, N ;
Jakobsson, R ;
Pershagen, G .
EPIDEMIOLOGY, 2000, 11 (05) :487-495
[23]  
OSTMAN C, 1989, FUEL, P1248
[24]   A HYDROXYLAPATITE MICROASSAY FOR RECEPTOR-BINDING OF 2,3,7,8-TETRACHLORODIBENZO-PARA-DIOXIN AND 3-METHYLCHOLANTHRENE IN VARIOUS TARGET TISSUES [J].
POELLINGER, L ;
LUND, J ;
DAHLBERG, E ;
GUSTAFSSON, JA .
ANALYTICAL BIOCHEMISTRY, 1985, 144 (02) :371-384
[25]  
SCHUETZLE D, 1986, CARCINOGENIC MUTAGEN, P41
[26]  
*SFS, 1957, SWED FISC EN TAX LEG, P262
[27]   VOLATILE ORGANIC-COMPOUND EMISSIONS FROM 46 IN-USE PASSENGER CARS [J].
SIGSBY, JE ;
TEJADA, S ;
RAY, W ;
LANG, JM ;
DUNCAN, JW .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1987, 21 (05) :466-475
[28]  
SJODIN A, 2000, PROCEEDINGS, V70
[29]   Influence of physical and chemical characteristics of diesel fuels and exhaust emissions on biological effects of particle extracts: A multivariate statistical analysis of ten diesel fuels [J].
Sjogren, M ;
Li, H ;
Banner, C ;
Rafter, J ;
Westerholm, R ;
Rannug, U .
CHEMICAL RESEARCH IN TOXICOLOGY, 1996, 9 (01) :197-207
[30]   Relevance of different biological assays in assessing initiating and promoting properties of polycyclic aromatic hydrocarbons with respect to carcinogenic potency [J].
Sjogren, M ;
Ehrenberg, L ;
Rannug, U .
MUTATION RESEARCH-FUNDAMENTAL AND MOLECULAR MECHANISMS OF MUTAGENESIS, 1996, 358 (01) :97-112