Towards "mechanochemistry":: Mechanically induced isomerizations of thiolate-gold clusters

被引：62

作者：

Krüger, D

Rousseau, R

Fuchs, H

Marx, D ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Theoret Chem, D-44780 Bochum, Germany

[2] Univ Munster, Inst Phys, D-48149 Munster, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 20期

关键词：

chemisorption; cluster compounds; gold; molecular electronics; nanostructures;

D O I：

10.1002/anie.200351000

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stretching the imagination: Based on simulations it is proposed that atommanipulation techniques, such as atomic force microscopy (AFM), could be used t, draw and manipulate monoatomic nano wires using thiolates anchored to gold clusters on surfaces (see picture, gold Au, yellow S). At the same time, the forceversus-extension curve is diagnostic for the isomerizations of the underlying covalently bound species.

引用

页码：2251 / 2253

页数：3

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