Maximizing Field-Effect Mobility and Solid-State Luminescence in Organic Semiconductors

被引：137

作者：

Dadvand, Afshin ^{[1
,2
]}

Moiseev, Andrey G. ^{[1
,2
]}

Sawabe, Kosuke ^{[3
,4
]}

Sun, Wei-Hsin ^{[1
,2
]}

Djukic, Brandon ^{[1
,2
]}

Chung, Insik ^{[1
,2
]}

Takenobu, Taishi ^{[4
]}

Rosei, Federico

Perepichka, Dmitrii F. ^{[1
,2
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

[2] McGill Univ, Ctr Self Assembled Chem Struct, Montreal, PQ H3A 2K6, Canada

[3] Tohoku Univ, Dept Phys, Grad Sch Sci, Sendai, Miyagi 980, Japan

[4] Waseda Univ, Grad Sch Adv Sci & Engn, Tokyo, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 16期

基金：

加拿大自然科学与工程研究理事会;

关键词：

anthracenes; luminescence; semiconductors; singlet fission; transistors; THIN-FILM TRANSISTORS; LIGHT-EMITTING-DIODES; N-TYPE; CRYSTAL; PENTACENE; EMISSION; SINGLET; PERFORMANCE; DERIVATIVES; ENERGY;

D O I：

10.1002/anie.201108184

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conductive and emissive: Organic transistors made from a simple styrylanthracene derivative (see scheme) have high charge mobility and high luminescence quantum yields. These properties are attributed to the lack of singlet fission, and challenge the idea that the efficient π interactions required for high mobility always lead to quenching of emission. The transistors emit blue electroluminescence and are stable during operation and storage. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3837 / 3841

页数：5

共 46 条

[31] Optical properties of oligo(9,9-diarylfluorene) derivatives in thin films and their application for organic light-emitting field-effect transistors [J].

Oyamada, Takahito ;

Chang, Chih-Hao ;

Chao, Teng-Chih ;

Fang, Fu-Chuan ;

Wu, Chung-Chih ;

Wong, Ken-Tsung ;

Sasabe, Hiroyuki ;

Adachi, Chihaya .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (01) :108-115

[32] Light-emitting polythiophenes [J].

Perepichka, IF ;

Perepichka, DF ;

Meng, H ;

Wudl, F .

ADVANCED MATERIALS, 2005, 17 (19) :2281-2305

[33] Pentacene disproportionation during sublimation for field-effect transistors [J].

Roberson, LB ;

Kowalik, J ;

Tolbert, LM ;

Kloc, C ;

Zeis, R ;

Chi, XL ;

Fleming, R ;

Wilkins, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (09) :3069-3075

[34] Ambipolar light-emitting organic field-effect transistors using a wide-band-gap blue-emitting small molecule [J].

Sakanoue, Tomo ;

Yahiro, Masayuki ;

Adachi, Chihaya ;

Uchiuzou, Hiroyuki ;

Takahashi, Takayoshi ;

Toshimitsu, Akio .

APPLIED PHYSICS LETTERS, 2007, 90 (17)

[35] Organic semiconductor lasers [J].

Samuel, I. D. W. ;

Turnbull, G. A. .

CHEMICAL REVIEWS, 2007, 107 (04) :1272-1295

[36] ORGANIC PHOTONICS Spotlight on organic transistors [J].

Santato, Clara ;

Cicoira, Fabio ;

Martel, Richard .

NATURE PHOTONICS, 2011, 5 (07) :392-393

[37] INTERSYSTEM CROSSING TO BOTH LIGAND-LOCALIZED AND CHARGE-TRANSFER EXCITED-STATES IN MONONUCLEAR AND DINUCLEAR RUTHENIUM(II) DIIMINE COMPLEXES [J].

SHAW, JR ;

WEBB, RT ;

SCHMEHL, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (03) :1117-1123

[38] Reliability of Organic Field-Effect Transistors [J].

Sirringhaus, Henning .

ADVANCED MATERIALS, 2009, 21 (38-39) :3859-3873

[39] Singlet Fission [J].

Smith, Millicent B. ;

Michl, Josef .

CHEMICAL REVIEWS, 2010, 110 (11) :6891-6936

[40] From computational discovery to experimental characterization of a high hole mobility organic crystal [J].

Sokolov, Anatoliy N. ;

Atahan-Evrenk, Sule ;

Mondal, Rajib ;

Akkerman, Hylke B. ;

Sanchez-Carrera, Roel S. ;

Granados-Focil, Sergio ;

Schrier, Joshua ;

Mannsfeld, Stefan C. B. ;

Zoombelt, Arjan P. ;

Bao, Zhenan ;

Aspuru-Guzik, Alan .

NATURE COMMUNICATIONS, 2011, 2

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