Cu(II)-assisted oxidation of quinoline-2-carbaldehyde hydrazone to give [1,2,3]triazolo[1,5-α]quinoline:: The first example of Cu(I) complex containing [1,2,3]triazolo-ligand

被引：36

作者：

Xiang, Jing ^{[1
]}

Yin, Ye-Gao

Mei, Ping

机构：

[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China

[2] Yangtze Univ, Coll Chem & Evironm Engn, Jinzhou 434020, Hubei, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 10期

关键词：

crystal structure; 1,2,3]Triazolo[1,5-alpha]quinoline; luminescence; cu(1) complex;

D O I：

10.1016/j.inoche.2007.06.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, single crystal structure, luminescent and electrochemistry properties of a Cu(I) compound based on in situ formation ligand, namely [1,2,3]triazolo[1,5-alpha]quinoline(L1), are reported. Complex [(Cu4Br4)-Br-I(L1)(4)] (1) is the first example of Cu(I) species with [1,2,3]triazole-ligand and provides the direct evidence for Cu(II) role to the ring-closure of hydrazone. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1168 / 1171

页数：4

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