Supramolecular structural diversities in the metal-organic frameworks derived from pyridylamide ligands: studying the effects of ligating topologies, hydrogen bonding backbone of the ligands and counter anions

被引：32

作者：

Kumar, D. Krishna ^{[1
]}

Das, Amitava ^{[1
]}

Dastidar, Parthasarathi ^{[1
]}

机构：

[1] Cent Salt & Marine Chem Res Inst, Analyt Sci Discipline, Bhavnagar 364002, Gujarat, India

来源：

CRYSTENGCOMM | 2007年 / 9卷 / 07期

关键词：

D O I：

10.1039/b701782k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Six metal - organic frameworks (MOFs) namely [{(CH3COO)(mu-OOCH3) Zn}(2)(mu- L1)(2)](n) 1, [{(H2O)(2)Zn}(mu-L1)(4)} BF4](n) 2, [{(Cl)(2)Zn}(mu-L1)](n) 3, [{(NO3)(2)Cd(mu- L1)(2)} center dot nitrobenzene](n) 4, [{Cl2Zn(mu-L2)}](n) 5 and [{(NO3)(2)Cd}(mu-L2)(4)](n) 6 ( where L1 = N-(3-pyridyl) nicotinamide and L2 = N-(3-pyridyl) isonicotinamide) have been synthesized and crystallographically characterized. The main aim of this work is to study the effects of ligating topologies and hydrogen bonding backbone of the ligands and counter anions on the supramolecular structural diversities in the resulting MOFs. The structures of these MOFs are discussed in this context.

引用

页码：548 / 555

页数：8

共 83 条

[11] New series of organogelators derived from a combinatorial library of primary ammonium monocarboxylate salts [J].

Ballabh, Amar ;

Trivedi, Darshak R. ;

Dastidar, Parthasarathi .

CHEMISTRY OF MATERIALS, 2006, 18 (16) :3795-3800

[12]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[13]

2-Z

[14] Open-framework coordination complexes from hydrogen-bonded networks: toward host/guest complexes [J].

Beatty, AM .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :131-143

[15] Transition metal and organometallic anion complexation agents [J].

Beer, PD ;

Hayes, EJ .

COORDINATION CHEMISTRY REVIEWS, 2003, 240 (1-2) :167-189

[16] HYDROGEN-BOND-DIRECTED SELF-ASSEMBLY OF D-(+)-DIBENZOYL TARTARIC ACID AND 4-AMINOPYRIDINE - OPTICAL NONLINEARITIES AND STOICHIOMETRY-DEPENDENT NOVEL STRUCTURAL FEATURES [J].

BHATTACHARYA, S ;

DASTIDAR, P ;

ROW, TNG .

CHEMISTRY OF MATERIALS, 1994, 6 (04) :531-537

[17] Long-range chain orientation in 1-D co-ordination polymers as a function of anions and intermolecular aromatic interactions [J].

Blake, AJ ;

Baum, G ;

Champness, NR ;

Chung, SSM ;

Cooke, PA ;

Fenske, D ;

Khlobystov, AN ;

Lemenovskii, DA ;

Li, WS ;

Schröder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (23) :4285-4291

[18] Silver(I) coordination polymers containing heteroditopic ureidopyridine ligands: The role of ligand isomerism, hydrogen bonding, and stacking interactions [J].

Blondeau, P ;

van der Lee, A ;

Barboiu, M .

INORGANIC CHEMISTRY, 2005, 44 (16) :5649-5653

[19] Metal-organic anion receptors: Arranging urea hydrogen-bond donors to encapsulate sulfate ions [J].

Bondy, CR ;

Gale, PA ;

Loeb, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (16) :5030-5031

[20] Crystal engineering, where from? Where to? [J].

Braga, D .

CHEMICAL COMMUNICATIONS, 2003, (22) :2751-2754

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