Direct observations of Ge2Sb2Te5 recording marks in the phase-change disk

被引:15
作者
Naito, Muneyuki [1 ]
Ishimaru, Manabu [1 ]
Hirotsu, Yoshihiko [1 ]
Kojima, Rie [2 ]
Yamada, Noboru [2 ]
机构
[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan
[2] Panasonic Corp, Digital & Network Technol Dev Ctr, Osaka 5708501, Japan
关键词
LOCAL-STRUCTURE; CRYSTALLIZATION; FILMS; DIFFRACTION; MEMORY;
D O I
10.1063/1.3373419
中图分类号
O59 [应用物理学];
学科分类号
摘要
Atomistic structures of the Ge2Sb2Te5 thin film in the real phase-change disk have been investigated using transmission electron microscopy (TEM). As-deposited amorphous Ge2Sb2Te5 films were laser-irradiated for initialization (crystallization) and recording. Cross-sectional TEM observations revealed that the recording mark was fully amorphized by laser irradiation. A slight difference between the as-deposited and the laser irradiation-induced amorphous Ge2Sb2Te5 was observed in the intensity profile of nanobeam electron diffraction patterns and atomic pair distribution functions. This difference was attributed to structural relaxation of amorphous Ge2Sb2Te5, which gives rise to the alteration of chemical order. (C) 2010 American Institute of Physics. [doi:10.1063/1.3373419]
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页数:5
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共 26 条
[1]   Structural phase transitions on the nanoscale:: The crucial pattern in the phase-change materials Ge2Sb2Te5 and GeTe [J].
Akola, J. ;
Jones, R. O. .
PHYSICAL REVIEW B, 2007, 76 (23)
[2]   Application of bond constraint theory to the switchable optical memory material Ge2Sb2Te5 [J].
Baker, DA ;
Paesler, MA ;
Lucovsky, G ;
Agarwal, SC ;
Taylor, PC .
PHYSICAL REVIEW LETTERS, 2006, 96 (25)
[3]   A physics-based model of electrical conduction decrease with time in amorphous Ge2Sb2Te5 [J].
Boniardi, M. ;
Redaelli, A. ;
Pirovano, A. ;
Tortorelli, I. ;
Ielmini, D. ;
Pellizzer, F. .
JOURNAL OF APPLIED PHYSICS, 2009, 105 (08)
[4]   Coexistence of tetrahedral- and octahedral-like sites in amorphous phase change materials [J].
Caravati, S. ;
Bernasconi, M. ;
K hne, T. D. ;
Krack, M. ;
Parrinello, M. .
APPLIED PHYSICS LETTERS, 2007, 91 (17)
[5]   Structural transformations of Ge2Sb2Te5 films studied by electrical resistance measurements [J].
Friedrich, I ;
Weidenhof, V ;
Njoroge, W ;
Franz, P ;
Wuttig, M .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (09) :4130-4134
[6]   Microscopic origin of the fast crystallization ability of Ge-Sb-Te phase-change memory materials [J].
Hegedus, J. ;
Elliott, S. R. .
NATURE MATERIALS, 2008, 7 (05) :399-405
[7]   Application of nano-diffraction to local atomic distribution function analysis of amorphous materials [J].
Hirotsu, Y ;
Ishimaru, M ;
Ohkubo, T ;
Hanada, T ;
Sugiyama, M .
JOURNAL OF ELECTRON MICROSCOPY, 2001, 50 (06) :435-442
[8]   Reliability Impact of Chalcogenide-Structure Relaxation in Phase-Change Memory (PCM) Cells-Part I: Experimental Study [J].
Ielmini, Daniele ;
Sharma, Deepak ;
Lavizzari, Simone ;
Lacaita, Andrea L. .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2009, 56 (05) :1070-1077
[9]   'Wrong bonds' in sputtered amorphous Ge2Sb2Te5 [J].
Jovari, P. ;
Kaban, I. ;
Steiner, J. ;
Beuneu, B. ;
Schops, A. ;
Webb, A. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (33)
[10]   Crystallization behavior of as-deposited, melt quenched, and primed amorphous states of Ge2Sb2.3Te5 films [J].
Khulbe, PK ;
Wright, EM ;
Mansuripur, M .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (07) :3926-3933