Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes

被引：89

作者：

Arnold, PL ^{[1
]}

Rodden, M ^{[1
]}

Wilson, C ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 13期

关键词：

D O I：

10.1039/b418302a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkoxide-functionalised N-heterocyclic carbenes (NHCs) stabilise the potassium-imidazole-2-ylidene fragment against 1,2 alkyl rearrangement reactions; this allows the first structural characterisation of a potassium NHC complex, which reveals distorted and unusual bonding interactions between the imidazole ring and the potassium cation.

引用

页码：1743 / 1745

页数：3

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