Raman scattering study of PbTiO3 and TiO2 obtained by sol-gel

被引:27
作者
Bersani, D
Lottici, PP
Lopez, T
Ding, XZ
机构
[1] Univ Parma, Ist Nazl Fis Mat, I-43100 Parma, Italy
[2] Univ Parma, Dept Phys, I-43100 Parma, Italy
[3] Univ Autonoma Metropolitana Iztapalapa, Dept Quim, Mexico City 09340, DF, Mexico
[4] Chinese Acad Sci, Shanghai Inst Met, Ion Beam Lab, Shanghai 200050, Peoples R China
关键词
Raman; TiO2; PbTiO3-nanocrystals;
D O I
10.1023/A:1008602718987
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The mechanisms that give rise to the broadening and the shifts of the Raman peaks of titanium dioxide and lead titanate nanocrystals prepared by sol-gel are discussed. Phonon confinement and oxygen deficiency are competitive mechanisms in TiO2 obtained by different sol-gel preparations whereas pressure effects on the nanocrystals predominate in ferroelectric PbTiO3.
引用
收藏
页码:849 / 853
页数:5
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