Self-Assembly of Pt(II) Spherical Complexes via Temporary Labilization of the Metal-Ligand Association in 2,2,2-Trifluoroethanol

被引：97

作者：

Fujita, Daishi

Takahashi, Asana

Sato, Sota

Fujita, Makoto ^{[1
]}

机构：

[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 34期

关键词：

IONIZATION MASS-SPECTROMETRY; COMPONENTS;

D O I：

10.1021/ja2059236

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermodynamically controlled platinum(II) spherical complexes were synthesized via temporary labilization of inert Pt(II)-pyridine bonds by the addition of the strong hydrogen-bond donor 2,2,2-trifluoroethanol (TFE), which weakens the pyridine metal interaction. The platinum complex was stably trapped after removal of TFE and showed higher acid durability than its palladium counterpart.

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页码：13317 / 13319

页数：3

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