24-Fold endohedral functionalization of a self-assembled M12L24 coordination nanoball

被引：155

作者：

Tominaga, M ^{[1
]}

Suzuki, K ^{[1
]}

Murase, T ^{[1
]}

Fujita, M ^{[1
]}

机构：

[1] Univ Tokyo, CREST, Japan Sci & Technol Corp, Sch Engn,Dept Appl Chem,Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 34期

关键词：

D O I：

10.1021/ja054069o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A ca. 5 nm-sized, roughly spherical hollow complex was assembled from 12 Pd2+ ions and 24 bis(4-pyridylethenyl)-substituted bent ligands. By putting a functional group at the curvature of the ligand, the 24 functional groups were precisely arrayed inward within the spherical complex. When oligo(ethylene oxide) was anchored, the void of the hollow complex was tightly filled with a pseudo poly(ethylene oxide) nanoparticle, which showed metal ion (La3+) absorption property. Copyright © 2005 American Chemical Society.

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页码：11950 / 11951

页数：2

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