A highly water-soluble dendro[60]fullerene

被引：235

作者：

Brettreich, M ^{[1
]}

Hirsch, A ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(98)00491-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

The nucleophilic cyclopropanation of C-60 With a second generation bis(polyamide)-malonate dendrimer and the subsequent deprotection of the terminal t-butyl groups provides a dendro[60]fullerene with 18 carboxylic groups in the periphery. This dendritic monoadduct of C-60 is highly water-soluble. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：2731 / 2734

页数：4

共 17 条

[1]

Sequence-specific modification of guanosine in DNA by a C-60-linked deoxyoligonucleotide: Evidence for a non-singlet oxygen mechanism [J].

An, YZ ;

Chen, CHB ;

Anderson, JL ;

Sigman, DS ;

Foote, CS ;

Rubin, Y .

TETRAHEDRON, 1996, 52 (14) :5179-5189

[2]

BOUTORINE AS, 1994, ANGEW CHEM INT EDIT, V33, P2462

[3]

Efficient cyclopropanation of C-60 starting from malonates [J].

Camps, X ;

Hirsch, A .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (11) :1595-1596

[4]

The C-60 core: A versatile tecton for dendrimer chemistry [J].

Camps, X ;

Schonberger, H ;

Hirsch, A .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (04) :561-567

[5]

EFFICIENT SYNTHESIS OF POLYHYDROXYLATED FULLERENE DERIVATIVES VIA HYDROLYSIS OF POLYCYCLOSULFATED PRECURSORS [J].

CHIANG, LY ;

WANG, LY ;

SWIRCZEWSKI, JW ;

SOLED, S ;

CAMERON, S .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (14) :3960-3968

[6]

Easy access to water-soluble fullerene derivatives via 1,3-dipolar cycloadditions of azomethine ylides to C-60 [J].

DaRos, T ;

Prato, M ;

Novello, F ;

Maggini, M ;

Banfi, E .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (25) :9070-9072

[7]

Carboxyfullerenes as neuroprotective agents [J].

Dugan, LL ;

Turetsky, DM ;

Du, C ;

Lobner, D ;

Wheeler, M ;

Almli, CR ;

Shen, CKF ;

Luh, TY ;

Choi, DW ;

Lin, TS .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1997, 94 (17) :9434-9439

[8]

Electron transfer to buckminster-fullerenes and functionalized fullerene derivatives in aqueous and protic media, as studied by radiolytic techniques [J].

Guldi, DM .

RESEARCH ON CHEMICAL INTERMEDIATES, 1997, 23 (07) :653-673

[9]

HIRSCH A, 1995, CHEM FULLERENES

[10]

RADICAL REACTIONS OF C60 [J].

KRUSIC, PJ ;

WASSERMAN, E ;

KEIZER, PN ;

MORTON, JR ;

PRESTON, KF .

SCIENCE, 1991, 254 (5035) :1183-1185

← 1 2 →