Adlayers of C60-C60 and C60-C70 fullerene dimers formed on Au(111) in benzene solutions studied by STM and LEED

被引：21

作者：

Matsumoto, M

Inukai, J

Tsutsumi, E

Yoshimoto, S

Itaya, K

Ito, O

Fujiwara, K

Murata, M

Murata, Y

Komatsu, K

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Appl Chem, Sendai, Miyagi 9808579, Japan

[2] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

[3] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan

[4] JST, CREST, Kawaguchi, Saitama 3320012, Japan

[5] Tohoku Univ, New Ind Creat Hatchery Ctr, NICHe, Sendai, Miyagi 9808579, Japan

来源：

LANGMUIR | 2004年 / 20卷 / 04期

关键词：

D O I：

10.1021/la0354537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Scanning tunneling microscopy (STM) and low-energy electron diffraction were used to reveal the structures of ordered adlayers of [2+2]-type C-60-C-60 fullerene dimer (C-120) and C-60-C-70 cross-dimer (C-130) formed on Au(111) by immersingit in a benzene solution containing C-120 or C-130 molecules. High-resolution STM images clearly showed the packing arrangements and the electronic structures Of C-120 and C-130 on the Au(111) surface in ultrahigh vacuum. The (2root3 x 4root3)R30degrees, (2root3 x 5root3)R30degrees, and (7 x 7) structures were found for the C-120 adlayer on the Au(111) surface, whereas C-130 molecules were closely packed on the surface. Each C-60 or C-70 monomer cage was discerned in the STM image of a C-130 molecule.

引用

页码：1245 / 1250

页数：6

共 31 条

[1] DETERMINATION OF THE ORIENTATION OF C-60 ADSORBED ON AU(111) AND AG(111) [J].