The selective formation of neutral, heteroleptic zinc(II) complexes via self-discrimination of chiral bisoxazoline racemates and pseudoracemates

被引：50

作者：

Takacs, JM ^{[1
]}

Hrvatin, PM

Atkins, JM

Reddy, DS

Clark, JL

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

[2] Univ Nebraska, Ctr Mat Res & Anal, Lincoln, NE 68588 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2005年 / 29卷 / 02期

关键词：

D O I：

10.1039/b413439g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible metal-directed multi-component self-assembly of chiral bisoxazolines proceeds with a high level of chiral self-discrimination and thus defines a simple strategy for the preparation of neutral, heteroleptic zinc(II) complexes.

引用

页码：263 / 265

页数：3

共 46 条

[21]

2-6

[22] Self-discrimination of the racemic ligands in the self-assembly of [{(dppp)Pt(L)}2]4+ [J].

Kim, TW ;

Lah, MS ;

Hong, JI .

CHEMICAL COMMUNICATIONS, 2001, (08) :743-744

[23] SELF-RECOGNITION IN HELICATE SELF-ASSEMBLY - SPONTANEOUS FORMATION OF HELICAL METAL-COMPLEXES FROM MIXTURES OF LIGANDS AND METAL-IONS [J].

KRAMER, R ;

LEHN, JM ;

MARQUISRIGAULT, A .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1993, 90 (12) :5394-5398

[24] First chiral organometallic triangle for asymmetric catalysis [J].

Lee, SJ ;

Hu, AG ;

Lin, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (44) :12948-12949

[25]

Lehn J.-M., 1995, Supramolecular Chemistry: Concepts and Prospectives

[26] Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].

Leininger, S ;

Olenyuk, B ;

Stang, PJ .

CHEMICAL REVIEWS, 2000, 100 (03) :853-907

[27] Supramolecular coordination compounds with chiral pyridine and polypyridine ligands derived from terpenes [J].

Mamula, O ;

von Zelewsky, A .

COORDINATION CHEMISTRY REVIEWS, 2003, 242 (1-2) :87-95

[28] Supramolecular chirality of self-assembled systems in solution [J].

Mateos-Timoneda, MA ;

Crego-Calama, M ;

Reinhoudt, DN .

CHEMICAL SOCIETY REVIEWS, 2004, 33 (06) :363-372

[29] Symmetry breaking in asymmetric catalysis: Racemic catalysis to autocatalysis [J].

Mikami, K ;

Yamanaka, M .

CHEMICAL REVIEWS, 2003, 103 (08) :3369-3400

[30] Metal ion complexes of the optically pure bi(4-phenyl-1,3-oxazoline) ligand. Synthesis, characterization and X-ray crystal structures [J].

Patra, GK ;

Goldberg, I ;

Sarkar, A ;

Chowdhury, S ;

Datta, D .

INORGANICA CHIMICA ACTA, 2003, 344 :7-14

← 1 2 3 4 5 →