A mesoporous Pt/TiO2 nanoarchitecture with catalytic and photocatalytic functions

被引:144
作者
Wang, XC
Yu, JC [1 ]
Yip, HY
Wu, L
Wong, PK
Lai, SY
机构
[1] Chinese Univ Hong Kong, Environm Sci Programme, Shatin, Hong Kong, Peoples R China
[2] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
[3] Chinese Univ Hong Kong, Dept Biol, Shatin, Hong Kong, Peoples R China
[4] Hong Kong Baptist Univ, Dept Chem, Kowloon, Hong Kong, Peoples R China
关键词
heterogeneous catalysis; mesoporous materials; photocatalysis; platinum; thin films;
D O I
10.1002/chem.200401248
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel metal/semiconductor nanocomposite with catalytic and photocatalytic functions has been prepared. The new material consists of highly dispersed platinum (Pt) nanoparticles embedded in a cubic mesoporous nanocrystalline anatase (meso-nc-TiO2) thin film. The porous thin film possesses a narrow pore-size distribution and a large surface area. The diameter of the Pt cluster can be controlled to below 5 nm, and the high dispersion of these clusters gives rise to catalytic activity for the oxidation of carbon monoxide, an important reaction for automobile exhaust treatment. This novel ordered mesoporous Pt/TiO2 nanoarchitecture is also a promising photochemical material, as demonstrated by the photo-driven killing of Micrococcus lylae cells on the film.
引用
收藏
页码:2997 / 3004
页数:8
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