Synthesis and characterization of a bipolar light-emitting copolymer consisting of tetraphenyldiaminobiphenyl and bis-quinoline units

被引：60

作者：

Liu, YQ ^{[1
]}

Ma, H ^{[1
]}

Jen, AKY ^{[1
]}

机构：

[1] Northeastern Univ, Dept Chem, Boston, MA 02115 USA

来源：

CHEMISTRY OF MATERIALS | 1999年 / 11卷 / 01期

关键词：

D O I：

10.1021/cm980628x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new luminescent copolymer containing both an efficient hole-transporting moiety, tetraphenyldiaminobiphenyl, and an electron-affinitive light-emitting moiety, bisquinoline, was prepared. It possesses high thermal stability (decomposes at temperatures above 461 degrees C), excellent electrochemical reversibility, good thin-film-forming ability, and bright light-emitting property. Electrical characterization of a two-layer diode device based on the structure of ITO/CuPc/TPD-PQ/Al showed excellent electroluminescence performance (bright yellow emission, a rectification ratio greater than 10(5), and a low turn-on voltage of 3.8 V).

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页码：27 / +

页数：4

相关论文

共 21 条

[1] MOLECULAR DESIGN OF HOLE TRANSPORT MATERIALS FOR OBTAINING HIGH DURABILITY IN ORGANIC ELECTROLUMINESCENT DIODES [J].

ADACHI, C ;

NAGAI, K ;

TAMOTO, N .

APPLIED PHYSICS LETTERS, 1995, 66 (20) :2679-2681

[2] SYNTHESIS AND PROCESSING OF HETEROCYCLIC POLYMERS AS ELECTRONIC, OPTOELECTRONIC, AND NONLINEAR OPTICAL-MATERIALS .2. NEW SERIES OF CONJUGATED RIGID-ROD POLYQUINOLINES AND POLYANTHRAZOLINES [J].

AGRAWAL, AK ;

JENEKHE, SA .

MACROMOLECULES, 1993, 26 (05) :895-905

[3] LIGHT-EMITTING-DIODES WITH VARIABLE COLORS FROM POLYMER BLENDS [J].

BERGGREN, M ;

INGANAS, O ;

GUSTAFSSON, G ;

RASMUSSON, J ;

ANDERSSON, MR ;

HJERTBERG, T ;

WENNERSTROM, O .

NATURE, 1994, 372 (6505) :444-446

[4] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[5] A novel class of nonlinear optical side-chain polymer: Polyquinolines with large second-order nonlinearity and thermal stability [J].

Chen, TA ;

Jen, AKY ;

Cai, YM .

CHEMISTRY OF MATERIALS, 1996, 8 (03) :607-&

[6] FLEXIBLE LIGHT-EMITTING-DIODES MADE FROM SOLUBLE CONDUCTING POLYMERS [J].

GUSTAFSSON, G ;

CAO, Y ;

TREACY, GM ;

KLAVETTER, F ;

COLANERI, N ;

HEEGER, AJ .

NATURE, 1992, 357 (6378) :477-479

[7] High-performance polyquinolines with pendent high-temperature chromophores for second-order nonlinear optics [J].

Jen, AKY ;

Wu, XM ;

Ma, H .

CHEMISTRY OF MATERIALS, 1998, 10 (02) :471-+

[8] An electroluminescent device made with a new fluorescent dye containing 1,3,4-oxadiazole [J].

Jiang, XZ ;

Liu, YQ ;

Tian, H ;

Qiu, WF ;

Song, XQ ;

Zhu, DB .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (08) :1395-1398

[9]

Kraft A, 1998, ANGEW CHEM INT EDIT, V37, P402, DOI 10.1002/(SICI)1521-3773(19980302)37:4<402::AID-ANIE402>3.0.CO

[10]

2-9