Steric engineering of C-F activation with lanthanoid formamidinates

被引：49

作者：

Cole, ML ^{[1
]}

Deacon, GB ^{[1
]}

Junk, PC ^{[1
]}

Konstas, K ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 12期

关键词：

D O I：

10.1039/b419047e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of lanthanum with Hg(C6F5)(2) and bulky N, N'-bis(2,6-diisopropylphenyl) formamidine (HDippForm) in tetrahydrofuran gives [LaF{DippForm}(2)(THF)] with a rare terminal Ln-F bond, and a high yield of a novel functionalised formamidine, DippForm((CH2)(4)OC6F4H-o).

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页码：1581 / 1583

页数：3

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