An interesting isotope effect in the Raman excitation profile for HI

被引:4
作者
Chakrabarti, N
Sathyamurthy, N [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] SN Bose Natl Ctr Basic Sci, Calcutta 700064, W Bengal, India
关键词
D O I
10.1021/jp982104q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is shown that the Raman excitation profile for the fundamental Stokes transition of DI in the vicinity of its electronic transition to the nearby dissociative states exhibits a larger deenhancement than that for HI, as a result of larger interference between the resonance Raman amplitudes for the four closely lying excited (dissociative) electronic states.
引用
收藏
页码:7089 / 7092
页数:4
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