Facile synthesis of a comb-like mannohexaose:: a trimer of the disaccharide repeating unit of the cell-wall mannans of Aphanoascus mephitatus and related species

被引:13
作者
Heng, LS [1 ]
Ning, J [1 ]
Kong, FZ [1 ]
机构
[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China
基金
中国国家自然科学基金;
关键词
comb-like oligosaccharide; synthesis; mannose;
D O I
10.1016/S0008-6215(01)00059-3
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
An efficient method for the preparation of a comb-like mannohexaose having alpha-(1 --> 6) and alpha-(1 --> 2) linkages has been described using 6-O-acetyl-2-O-benzoyl-3,4-di-O-benzyl-alpha -D-mannopyranosyl trichloroacetimidate as the key glycosyl donor in an 'inverse Schmidt' procedure. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:431 / 437
页数:7
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