Unimolecular dissociation of HCO .3. Comparison of calculated and measured CO rotational-state distributions

被引：15

作者：

Keller, HM ^{[1
]}

Schinke, R ^{[1
]}

机构：

[1] MAX PLANCK INST STROMUNGSFORSCH,D-37073 GOTTINGEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1997年 / 93卷 / 05期

关键词：

D O I：

10.1039/a606681j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present calculations for the unimolecular dissociation of HCO in the electronic ground state for total angular momenta J = 1 and 3. The calculated rotational-state distributions for CO are compared with recent experimental results and the agreement is found to be excellent. Of particular interest is the influence of the overall rotation of the parent molecule. It is demonstrated how the final rotational-state distributions reflect the angular dependence of the wavefunction at the transition state.

引用

页码：879 / 884

页数：6

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