Polyoxometalates: Powerful Catalysts for Atom-Efficient Cyclopropanations

被引：13

作者：

Boldini, Irene ^{[2
,3
]}

Guillemot, Geoffroy ^{[1
]}

Caselli, Alessandro ^{[2
,3
]}

Proust, Anna ^{[1
,4
]}

Gallo, Emma ^{[2
,3
]}

机构：

[1] Univ Paris 06, UMR CNRS 7201, Inst Parisien Chim Mol, F-75252 Paris 05, France

[2] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Analit La, I-20133 Milan, Italy

[3] ISTM CNR, I-20133 Milan, Italy

[4] Inst Univ France, F-75005 Paris, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 14-15期

关键词：

cobalt; copper; cyclopropanes; diazo compounds; homogeneous catalysis; polyoxometalates; DICOPPER-SUBSTITUTED SILICOTUNGSTATE; HETEROPOLYMETALATE CLUSTERS; HYDROGEN-PEROXIDE; NONPOLAR-SOLVENTS; OXIDATION; OLEFINS; COMPLEXES; OXYGEN; EPOXIDATION; ACID;

D O I：

10.1002/adsc.201000378

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The polyoxometalate-based catalytic cyclopropanation of olefins by ethyl diazoacetate (EDA) is reported. The outstanding catalyst productivity (TONs up to 100,000) and the use of equimolar EDA/olefin ratio confer to the methodology a high sustainability. Preliminary mechanistic investigations are also discussed.

引用

页码：2365 / 2370

页数：6

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