Tandem pinacol coupling - rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate

被引：15

作者：

Branytska, Olena

Shimon, Linda J. W.

Neumann, Ronny ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

[2] Weizmann Inst Sci, Chem Res Support Unit, IL-76100 Rehovot, Israel

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 38期

关键词：

D O I：

10.1039/b710100g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Together with a strongly oxidizing polyoxometalate, H5PV2-Mo10O40, Pt-II(N-(2,6-diisopropylphenyl)pyrazin-2-ylmethanimine)Cl-2 forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.

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页码：3957 / 3959

页数：3

相关论文

共 44 条

[1] Samarium diiodide-catalyzed diastereoselective pinacol couplings [J].

Aspinall, HC ;

Greeves, N ;

Valla, C .

ORGANIC LETTERS, 2005, 7 (10) :1919-1922

[2] Mild, aqueous, aerobic, catalytic oxidation of methane to methanol and acetaldehyde catalyzed by a supported bipyrimidinylplatinum-polyoxometalate hybrid compound [J].

Bar-Nahum, I ;

Khenkin, AM ;

Neumann, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (33) :10236-10237

[3] Organometallic-polyoxometalate hybrid compounds: Metallosalen compounds modified by Keggin type polyoxometalates [J].

Bar-Nahum, I ;

Cohen, H ;

Neumann, R .

INORGANIC CHEMISTRY, 2003, 42 (11) :3677-3684

[4] Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic-polyoxometalate hybrid compound [J].

Bar-Nahum, I ;

Neumann, R .

CHEMICAL COMMUNICATIONS, 2003, (21) :2690-2691

[5] Selective aerobic oxidation of alcohols with a combination of a polyoxometalate and nitroxyl radical as catalysts [J].

Ben-Daniel, R ;

Alsters, P ;

Neumann, R .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (25) :8650-8653

[6] Aerobic oxidations of conjugated dienes using a catalytic palladium(II)-quinone-heteropolyacid system for electron transfer from organic substrates to molecular oxygen [J].

Bergstad, K ;

Grennberg, H ;

Backvall, JE .

ORGANOMETALLICS, 1998, 17 (01) :45-50

[7] The remarkable role of water during the chemoselective reduction of ketones mediated by metallic aluminium [J].

Bhar, S ;

Guha, S .

TETRAHEDRON LETTERS, 2004, 45 (19) :3775-3777

[8] NEW REAGENTS FOR INTERMOLECULAR AND INTRAMOLECULAR PINACOLIC COUPLING OF KETONES AND ALDEHYDES [J].

COREY, EJ ;

DANHEISER, RL ;

CHANDRASEKARAN, S .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (02) :260-265

[9] TITANIUM-CATALYZED REDUCTIVE CYCLIZATION OF DELTA,EPSILON-UNSATURATED KETONES AND ALDEHYDES [J].

CROWE, WE ;

RACHITA, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (25) :6787-6788

[10]

Fittig R., 1859, LIEBIGS ANN CHEM, V110, P23

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