Tandem pinacol coupling - rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate

被引：15

作者：

Branytska, Olena

Shimon, Linda J. W.

Neumann, Ronny ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

[2] Weizmann Inst Sci, Chem Res Support Unit, IL-76100 Rehovot, Israel

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 38期

关键词：

D O I：

10.1039/b710100g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Together with a strongly oxidizing polyoxometalate, H5PV2-Mo10O40, Pt-II(N-(2,6-diisopropylphenyl)pyrazin-2-ylmethanimine)Cl-2 forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.

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页码：3957 / 3959

页数：3

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