Bis(oxazoline) derived cationic aqua complexes: highly effective catalysts for enantioselective Diels-Alder reactions

被引：57

作者：

Ghosh, AK ^{[1
]}

Cho, H ^{[1
]}

Cappiello, J ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 20期

关键词：

D O I：

10.1016/S0957-4166(98)00362-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic aqua complex derived from bidentate inda-box ligand and Cu(ClO4)(2). 6H(2)O is an excellent catalyst (5-10 mol%) for enantioselective (92-99% ee) Diels-Alder reactions of cyclopentadiene and various bidentate dienophiles. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：3687 / 3691

页数：5

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