The complete Raman spectrum of nanometric SnO2 particles

被引:724
作者
Diéguez, A [1 ]
Romano-Rodríguez, A [1 ]
Vilà, A [1 ]
Morante, JR [1 ]
机构
[1] Univ Barcelona, Dept Elect, E-08028 Barcelona, Spain
关键词
D O I
10.1063/1.1385573
中图分类号
O59 [应用物理学];
学科分类号
摘要
The complete Raman spectrum of SnO2 nanoparticles in presented and analyzed. In addition to the "classical" modes observed in the rutile structure, two other regions shown Raman activity for nanoparticles. The Raman bands in the low-frequency region are attributed to acoustic modes associated with the vibration of the individual nanoparticle as a whole. The high-frequency region is activated by surface disorder. A detailed analysis of these regions and the changes in the normal modes of SnO2 are presented as a function nanoparticle size. (C) 2001 American Institute of Physics.
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页码:1550 / 1557
页数:8
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