A Charge/Discharge Device for Chemical Hydrogen Storage and Generation

被引：124

作者：

Papp, Gabor ^{[1
]}

Csorba, Jeno ^{[1
]}

Laurenczy, Gabor ^{[2
]}

Joo, Ferenc ^{[1
]}

机构：

[1] Univ Debrecen, Hungarian Acad Sci, Inst Phys Chem, Res Grp Homogeneous Catalysis, H-4010 Debrecen, Hungary

[2] Ecole Polytech Fed Lausanne, ISIC LCOM Grp Catalysis Energy & Environm, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 44期

基金：

瑞士国家科学基金会;

关键词：

fuel cells; homogeneous catalysis; hydrogen; hydrogenation; ruthenium; FORMIC-ACID DECOMPOSITION; CARBON-DIOXIDE; AQUEOUS-SOLUTION; HOMOGENEOUS HYDROGENATION; COMPLEXES; FORMATE; CATALYST; BICARBONATES; SELECTIVITY; REDUCTION;

D O I：

10.1002/anie.201104951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Soda stream: Sodium bicarbonate was cyclically hydrogenated in aqueous solution to sodium formate at 100 bar H2 in the presence of a Ru II-sulfonated phosphine catalyst. The system functions as a true charge/discharge device for storage and delivery of hydrogen without the need for isolation of either formate or bicarbonate. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10433 / 10435

页数：3

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