CO2-"Neutral" Hydrogen Storage Based on Bicarbonates and Formates

被引：280

作者：

Boddien, Albert ^{[1
]}

Gaertner, Felix ^{[1
]}

Federsel, Christopher ^{[1
]}

Sponholz, Peter ^{[1
]}

Mellmann, Doerthe ^{[1
]}

Jackstell, Ralf ^{[1
]}

Junge, Henrik ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Leibniz Inst Katalyse eV, Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 28期

关键词：

bicarbonates; homogeneous catalysis; formates; hydrogen storage; ruthenium; FORMIC-ACID DECOMPOSITION; CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; CATALYZED HYDROGENATION; GENERATION; WATER; COMPLEXES; FUEL; TEMPERATURE; REDUCTION;

D O I：

10.1002/anie.201101995

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Let the circle be unbroken! One ruthenium catalyst generated in situ facilitates the selective hydrogenation of bicarbonates and carbonates, as well as CO2 and base, to give formates and also the selective dehydrogenation of formates back to bicarbonates. The two reactions can be coupled, leading to a reversible hydrogen-storage system. dppm=1,2- bis(diphenylphosphino)methane. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6411 / 6414

页数：4

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