Helical superstructure of conductive polymers as created by electrochemical polymerization by using synthetic lipid assemblies as a template

被引：86

作者：

Hatano, T

Bae, AH

Takeuchi, M

Fujita, N

Kaneko, K

Ihara, H

Takafuji, M

Shinkai, S ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

[2] Kyushu Univ, HVEM Lab, Fukuoka 8128581, Japan

[3] Kumamoto Univ, Grad Sch Sci & Technol, Dept Mat & Life Sci, Kumamoto 8608555, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 04期

关键词：

conducting materials; helical structures; lipids; polymerization; template synthesis;

D O I：

10.1002/anie.200351749

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A templating method is used to create conductive polymers that have a helical superstructure. The driving force is an electrostatic interaction between the negative charge in a synthetic lipid and the cationic charge generated in the polymers during oxidative electrochemical polymerization of ethylenedioxythiophene (EDOT) and a pyrrole (see picture; CV = cyclic voltammetry).

引用

页码：465 / 469

页数：5

共 44 条

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[Anonymous], ANGEW CHEM

[2] HELICAL AND TUBULAR MICROSTRUCTURES FORMED BY POLYMERIZABLE PHOSPHATIDYLCHOLINES [J].