Multiple pathway dynamics of the O(1D)+C2H6 reaction:: A crossed beam study

被引:25
作者
Shu, J [1 ]
Lin, JJ
Lee, YT
Yang, XM
机构
[1] Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei, Taiwan
[3] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan
关键词
D O I
10.1063/1.1380203
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The O(D-1)+C2H6 reaction has been reinvestigated using the improved universal crossed molecular beam technique. Four different reaction channels, OH+C2H5, CH3+H2COH/H3CO, H+H4C2OH/H5C2O and H-2+H3C2OH/H4C2O, are observed. Among these reaction channels, the CH3 formation channel is the dominant pathway and the OH formation is also a significant process, while the H and H-2 formation processes are minor. Different product angular distributions are also observed for these channels, indicating that the reaction product formation in these channels proceeds with distinctive reaction dynamics. (C) 2001 American Institute of Physics.
引用
收藏
页码:849 / 857
页数:9
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