Product state(s)-resolved differential cross section of the reaction O(D-1)+HD->OH(v,j)+D

被引:75
作者
Hsu, YT
Liu, KP
机构
[1] Inst. of Atom. and Molec. Sciences, Academia Sinica, Taipei
关键词
D O I
10.1063/1.474518
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Doppler-selected time-of-flight method was applied to map out directly the differential cross sections of the title reaction. These new results supersede those reported earlier from this laboratory using the conventional Doppler-shift technique. More significantly, clear structures are now revealed, which correspond to a series of subgroups of partially resolved states of OH(v,j). They offer considerable promise in unraveling the complicated dynamical attributes associated with the two microscopic pathways, insertion and abstraction, which play in this reaction. (C) 1997 American Institute of Physics.
引用
收藏
页码:1664 / 1667
页数:4
相关论文
共 19 条
[1]   Product state-resolved stereodynamics: Quasiclassical study of the reaction O(D-1)+HD->OH(OD) (v', j')+D(H) [J].
Alexander, AJ ;
Aoiz, FJ ;
Brouard, M ;
Simons, JP .
CHEMICAL PHYSICS LETTERS, 1996, 256 (06) :561-568
[2]   An experimental and quasiclassical study of the product state resolved stereodynamics of the reaction O(D-1(2))+H-2(v=0)->OH(X(2)Pi(3/2); v=0, N, f)+H [J].
Alexander, AJ ;
Aoiz, FJ ;
Brouard, M ;
Burak, I ;
Fujimura, Y ;
Short, J ;
Simons, JP .
CHEMICAL PHYSICS LETTERS, 1996, 262 (05) :589-597
[3]   VIBRATIONAL-EXCITATION OF OH(X2-PI) PRODUCED IN THE REACTION OF O(D-1) WITH H-2 [J].
BUTLER, JE ;
MACDONALD, RG ;
DONALDSON, DJ ;
SLOAN, JJ .
CHEMICAL PHYSICS LETTERS, 1983, 95 (03) :183-188
[4]   REACTION DYNAMICS OF O(1D2) + H-2, HD, D2-OH, OD(X2PI-I) PRODUCT INTERNAL ENERGY-DISTRIBUTIONS [J].
BUTLER, JE ;
JURSICH, GM ;
WATSON, IA ;
WIESENFELD, JR .
JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (10) :5365-5377
[5]   REACTIVE SCATTERING OF O(D-1)+HD - PRODUCT SPEED AND ANGLE DISTRIBUTIONS [J].
CHE, DC ;
LIU, KP .
JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (12) :5164-5167
[6]   F-D-2 state resolved reactive scattering at 180 and 240 meV collision energies .1. A high resolution crossed molecular beam experiment [J].
Faubel, M ;
MartinezHaya, B ;
Rusin, LY ;
Tappe, U ;
Toennies, JP ;
Aoiz, FJ ;
Banares, L .
CHEMICAL PHYSICS, 1996, 207 (2-3) :227-243
[7]  
HSU YT, IN PRESS J CHEM PHYS
[8]   Photodissociative pathways of C2H2 at 121.6 nm revealed by a Doppler-Selected time-of-flight (a 3-D mapping) technique [J].
Lai, LH ;
Che, DC ;
Liu, KP .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (16) :6376-6380
[9]   Direct mapping of vibrational-specific angular distributions of the polyatomic reaction product: CN+D-2->DCN+D [J].
Lai, LH ;
Wang, JH ;
Che, DC ;
Liu, KP .
JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (08) :3332-3335
[10]   STATE-TO-STATE INTEGRAL CROSS-SECTIONS FOR THE INELASTIC-SCATTERING OF CH(X2-PI) + HE - ROTATIONAL RAINBOW AND ORBITAL ALIGNMENT [J].
MACDONALD, RG ;
LIU, K .
JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (02) :821-838