Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries

被引：70

作者：

Constable, EC ^{[1
]}

Housecroft, CE

Kulke, T

Lazzarini, C

Schofield, ER

Zimmermann, Y

机构：

[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

[2] Inst Anorgan Chem, CH-4056 Basel, Switzerland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 19期

关键词：

D O I：

10.1039/b104865c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixing solutions of homoleptic cobalt(II) complexes [CoA(2)](2+) and [CoB2](2+) results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB](2+) By using enantiomorphic ligands A and B the reactions may be followed by H-1 NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4-substituted species.

引用

页码：2864 / 2871

页数：8

共 53 条

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