Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries

被引:70
作者
Constable, EC [1 ]
Housecroft, CE
Kulke, T
Lazzarini, C
Schofield, ER
Zimmermann, Y
机构
[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England
[2] Inst Anorgan Chem, CH-4056 Basel, Switzerland
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 19期
关键词
D O I
10.1039/b104865c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Mixing solutions of homoleptic cobalt(II) complexes [CoA(2)](2+) and [CoB2](2+) results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB](2+) By using enantiomorphic ligands A and B the reactions may be followed by H-1 NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4-substituted species.
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页码:2864 / 2871
页数:8
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