Kinetic and adsorption study of acid dye removal using activated carbon

被引:342
作者
Gomez, V. [1 ]
Larrechi, M. S. [1 ]
Callao, M. P. [1 ]
机构
[1] Univ Rovira & Virgili, Analyt & Organ Chem Dept, Tarragona 43007, Spain
关键词
activated carbon; adsorption; dye removal; kinetics; isotherms; wastewater;
D O I
10.1016/j.chemosphere.2007.03.076
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The adsorption of three acid dyes, Acid Red 97, Acid Orange 61 and Acid Brown 425 onto activated carbon was studied for the removal of acid dyes from aqueous solutions at room temperature (25 degrees C. The adsorption of each dye with respect to contact time was then measured to provide information about the adsorption characteristics of activated carbon. The rates of adsorption were found to conform to the pseudo-second-order kinetics with a good correlation. The experimental isotherms obtained, except for Acid Orange 61 studied in mixture, were of the S-type in terms of the classification of Giles and co-workers. The best fit of the adsorption isotherm data was obtained using the Freundlich model. When a comparative study was made of the results obtained with single and mixed dyes, it can be seen that some of them affect others and modify their behavior in the adsorption process. The results indicate that activated carbon Could be employed for the removal of dyes from wastewater. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1151 / 1158
页数:8
相关论文
共 34 条
[1]   Prediction of breakthrough curves for adsorption of complex organic solutes present in palm oil mill effluent (POME) on granular activated carbon [J].
Ahmad, A. L. ;
Chong, M. F. ;
Bhatia, S. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (20) :6793-6802
[2]   Investigation on the adsorption capability of egg shell membrane towards model textile dyes [J].
Arami, Mokhtar ;
Limaee, Nargess Yousefi ;
Mahmoodi, Niyaz Mohammad .
CHEMOSPHERE, 2006, 65 (11) :1999-2008
[3]   Removal of coloured organic matter by adsorption onto low-cost waste materials [J].
Bousher, A ;
Shen, XD ;
Edyvean, RGJ .
WATER RESEARCH, 1997, 31 (08) :2084-2092
[4]   Catalytic degradation of Orange II by UV-Fenton with hydroxyl-Fe-pillared bentonite in water [J].
Chen, Jianxin ;
Zhu, Lizhong .
CHEMOSPHERE, 2006, 65 (07) :1249-1255
[5]   Sorption of acid dyes from effluents using activated carbon [J].
Choy, KKH ;
McKay, G ;
Porter, JF .
RESOURCES CONSERVATION AND RECYCLING, 1999, 27 (1-2) :57-71
[6]   Single and multicomponent equilibrium studies for the adsorption of acidic dyes on carbon from effluents [J].
Choy, KKH ;
Porter, JF ;
McKay, G .
LANGMUIR, 2004, 20 (22) :9646-9656
[7]   Adsorption of Acid Red 73 on copper dithiocarbamate precipitate-type solid wastes [J].
Fu, Fenglian ;
Xiong, Ya ;
Xie, Baoping ;
Chen, Runming .
CHEMOSPHERE, 2007, 66 (01) :1-7
[8]   STUDIES IN ADSORPTION .11. A SYSTEM OF CLASSIFICATION OF SOLUTION ADSORPTION ISOTHERMS, AND ITS USE IN DIAGNOSIS OF ADSORPTION MECHANISMS AND IN MEASUREMENT OF SPECIFIC SURFACE AREAS OF SOLIDS [J].
GILES, CH ;
MACEWAN, TH ;
NAKHWA, SN ;
SMITH, D .
JOURNAL OF THE CHEMICAL SOCIETY, 1960, (OCT) :3973-3993
[9]   Sequential injection analysis with second-order treatment for the determination of dyes in the exhaustion process of tanning effluents [J].
Gomez, V. ;
Font, J. ;
Callao, M. P. .
TALANTA, 2007, 71 (03) :1393-1398
[10]   The kinetics of sorption of divalent metal ions onto sphagnum moss peat [J].
Ho, YS ;
McKay, G .
WATER RESEARCH, 2000, 34 (03) :735-742