A novel 2-D honeycomb-like lithium coordination polymer containing 42-membered rings

被引：32

作者：

Liu, X

Guo, GC ^{[1
]}

Liu, B

Chen, WT

Huang, JS

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2005年 / 5卷 / 03期

关键词：

D O I：

10.1021/cg049570r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of LiBr and bis(diphenylphosphineoxo)ethane (dppe-O) in tetrahydrofuran (THF) and further diffusion with n-pentane gave rise to a new coordination polymer formulated as [Li-2(dppe-O)(3)Br-2](n) and has been shown by X-ray diffraction analysis to be a 2-D noninterpenetrating honeycomb-like layer of (6,3) topology containing 42-membered rings with 1-D hydrophobic channels. These 2-D layers stack together tightly through weak hydrogen bonding and strong pi center dot center dot center dot pi stacking interactions to form a 3-D nanoporous structure.

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收藏

页码：841 / 843

页数：3

相关论文

共 44 条

[1] The C-H•••Cl hydrogen bond:: Does it exist? [J].

Aakeröy, CB ;

Evans, TA ;

Seddon, KR ;

Pálinkó, I .

NEW JOURNAL OF CHEMISTRY, 1999, 23 (02) :145-152

[2] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

MICHAIL, DM ;

ROBSON, R .

NATURE, 1994, 369 (6483) :727-729

[3]

ALRESAYES SI, 1991, J CHEM SOC CHEM COMM, P78

[4] Using long bis(4-pyridyl) ligands designed for the self-assembly of coordination frameworks and architectures [J].

Banfi, S ;

Carlucci, L ;

Caruso, E ;

Ciani, G ;

Proserpio, DM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (13) :2714-2721

[5] One-pot synthesis of a novel tridentate tin(IV) ligand; Syntheses and structures of [Bu(n)Sn(NC5H4-C,N)(3)MBr] (M=Li, Cu) [J].

Beswick, MA ;

Belle, CJ ;

Davies, MK ;

Halcrow, MA ;

Raithby, PR ;

Steiner, A ;

Wright, DS .

CHEMICAL COMMUNICATIONS, 1996, (23) :2619-2620

[6] Oxygen atom transfer from nitrogenous ReVO reagents to diphosphines and subsequent transformations.: Rhenium(III) products and reaction models [J].

Bhattacharyya, S ;

Chakraborty, I ;

Dirghangi, BK ;

Chakravorty, A .

INORGANIC CHEMISTRY, 2001, 40 (02) :286-293

[7] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[8]

Bu XH, 2001, ANGEW CHEM INT EDIT, V40, P3201, DOI 10.1002/1521-3773(20010903)40:17<3201::AID-ANIE3201>3.0.CO

[9]

2-Z

[10] Novel lanthanide(III) coordination polymers with 1,4-bis(phenyl-sulfinyl)butane forming unique lamellar square array: Syntheses, crystal structures, and properties [J].

Bu, XH ;

Weng, W ;

Du, M ;

Chen, W ;

Li, JR ;

Zhang, RH ;

Zhao, LJ .

INORGANIC CHEMISTRY, 2002, 41 (04) :1007-+

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