A novel 2-D honeycomb-like lithium coordination polymer containing 42-membered rings

被引：32

作者：

Liu, X

Guo, GC ^{[1
]}

Liu, B

Chen, WT

Huang, JS

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2005年 / 5卷 / 03期

关键词：

D O I：

10.1021/cg049570r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of LiBr and bis(diphenylphosphineoxo)ethane (dppe-O) in tetrahydrofuran (THF) and further diffusion with n-pentane gave rise to a new coordination polymer formulated as [Li-2(dppe-O)(3)Br-2](n) and has been shown by X-ray diffraction analysis to be a 2-D noninterpenetrating honeycomb-like layer of (6,3) topology containing 42-membered rings with 1-D hydrophobic channels. These 2-D layers stack together tightly through weak hydrogen bonding and strong pi center dot center dot center dot pi stacking interactions to form a 3-D nanoporous structure.

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收藏

页码：841 / 843

页数：3

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