Toward a molecular photochemical device: A triad for photoinduced charge separation based on a platinum diimine bis(acetylide) chromophore

被引：412

作者：

McGarrah, JE ^{[1
]}

Kim, YJ ^{[1
]}

Hissler, M ^{[1
]}

Eisenberg, R ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 18期

关键词：

D O I：

10.1021/ic015559u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A donor-chromophore-acceptor triad (D-C-A) in which the chromophore is a Pt diimine bis(acetylide) moiety (red), the donor is phenothiazine (blue), and the acceptor is nitrophenyl (green) has been synthesized and studied spectroscopically. Irradiation leads to a charge-separated state that has a 70 ns lifetime as measured by transient absorption spectroscopy.

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页码：4510 / 4511

页数：2

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